How Long’s Too Long? Effects of Crosslinker Length on Anion-Exchange Membrane Fuel Cells
Many efforts are being made worldwide to replace fossil fuels with greener alternatives. Hydrogen (H2) is a promising option that is currently in the spotlight; it can be used to generate electricity in fuel cells with water generated as the only byproduct. However, the technology is not quite ready for commercialization because proton-exchange membrane fuel cells, the most widely studied type, suffer from high cost and stability issues.
In contrast, anion-exchange membrane (AEM) fuel cells use cheaper catalysts and can offer superior performance. In these cells, hydroxide ions (OH−) are circulated instead of protons through the use of a polymer electrolyte composed of a polymer backbone and ion-conducting groups. One way to improve the properties of such electrolytes is by crosslinking—physically or chemically linking polymer units to each other through molecular side chains.
Although oxygen-containing crosslinkers improve the stability and ion conductivity of AEMs by virtue of their hydrophilicity, or affinity for water, the effects of crosslinker length, which defines the number of oxygen atoms, are not understood in detail.
To gain deeper insight into this issue, scientists at Incheon National University recently carried out a study where they prepared long AEM polymers with ammonium ion-conducting groups and bound these molecules together using ethylene oxide (EO)-containing crosslinkers of various lengths. Through a wide variety of experiments, they compared AEMs with different crosslinker lengths in terms of their mechanical and thermal properties, water retention capacity, OH− ion conductivity, morphology, and stability. Their findings are published in the Journal of Membrane Science, a top journal in the field of polymer science.
The experiments helped the scientists elucidate the mechanisms by which excessive crosslinker length can ultimately degrade the performance of AEMs. Professor Tae-Hyun Kim, who led the study, explains: “Though it was easy to predict that oxygen-containing crosslinkers would increase hydrophilicity and possibly lead to better ionic conductivity, our results reveal that an excessively large number of repeating oxygen units increases the crystallinity—or degree of order—of the resulting material. In turn, this actually reduces hydrophilicity and ultimately compromises many physicochemical properties of the AEM.”
After establishing the optimal length for their crosslinker, the researchers prepared an AEM fuel cell and found that the resulting performance was markedly better than when using AEMs without oxygen-containing crosslinkers. Excited about the results, Professor Kim comments: “The main takeaway from our study is that adding molecules with high water affinity, such as ethylene oxide, to crosslinkers of optimal length is a valid strategy to improve the fundamental properties of AEMs and their performance in actual fuel cells.”
Although there is still room for improvement before AEM fuel cells can be effectively used in practice and commercialized, this study takes our society a step further towards the popularization of next-generation ecofriendly energy sources.
Authors: Seounghwa Sung (1,2), T.S. Mayadevi (1,2), Kyungwhan Min (1,2), Junghwa Lee (1,2), Ji Eon Chae (3), Tae-Hyun Kim (1,2)
Title of original paper: Crosslinked PPO-based anion exchange membranes: The effect of crystallinity versus hydrophilicity by oxygen-containing crosslinker chain length
Journal: Journal of Membrane Science
(1) Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National University
(2) Research Institute of Basic Sciences, Incheon National University
(3) Fuel Cell Research Center, Korea Institute of Science and Technology
About Incheon National University
Incheon National University (INU) is a comprehensive, student-focused university. It was founded in 1979 and given university status in 1988. One of the largest universities in South Korea, it houses nearly 14,000 students and 500 faculty members. In 2010, INU merged with Incheon City College to expand capacity and open more curricula. With its commitment to academic excellence and an unrelenting devotion to innovative research, INU offers its students real-world internship experiences. INU not only focuses on studying and learning but also strives to provide a supportive environment for students to follow their passion, grow, and, as their slogan says, be INspired.
About the author
Dr Tae-Hyun Kim is a Chemistry Professor at Incheon National University (INU), Korea. He is also the director of the Research Institute of Basic Sciences at INU. Prof Kim received a Ph.D. in Chemistry from Cambridge University, UK and conducted his post-doctoral research at MIT, USA. Before joining INU, he was a senior research associate at Eastman Chemical Co., US. His research interests lie in the development of organic materials for various applications, including fuel cells, lithium batteries, water electrolysis, and gas separation. He has authored over 120 SCI journal articles and holds more than 50 patents. He loves teaching and communicating with his students.